SPECTRAL AND STRUCTURAL ANALYSIS FOR SODIUM SILICATE-BASED AEROGEL VIA NORMAL DRYING PRESSURE
Article Sidebar
Main Article Content
Abstract
Five types of silica aerogel were prepared at ambient pressure: sodium silicate, TEOS, and sodium silicate, with TEOS utilized as precursors. We investigated the effects of catalysis, mixing water or ethanol with the precursors, as well as the procedure of modification. Aqueous is a low-cost alternative, and many applications utilize it. A manufacturing colloidal silicic acid hydrosol was created from the ion exchange of an industrial water glass. The properties of physical, chemical, and hydrophobicity were examined via density, XRD, FTIR, and contact angle. BET, FESEM, and EDS analysis determined the structural properties. The silica hydrogel's pore liquid (H20) was successively removed. The spectral properties confirmed the modification by the derived high contact angle of 152º, low transparency, and amorphous structure. The resulting aerogel monoliths have a well-developed mesoporous structure, a large specific surface area of 961 m2/g, and a low density of 0.04 g/cm3.
Downloads
Article Details
Transfer of Copyrights
- In the event of publication of the manuscript entitled [INSERT MANUSCRIPT TITLE AND REF NO.] in the Malaysian Journal of Science, I hereby transfer copyrights of the manuscript title, abstract and contents to the Malaysian Journal of Science and the Faculty of Science, University of Malaya (as the publisher) for the full legal term of copyright and any renewals thereof throughout the world in any format, and any media for communication.
Conditions of Publication
- I hereby state that this manuscript to be published is an original work, unpublished in any form prior and I have obtained the necessary permission for the reproduction (or am the owner) of any images, illustrations, tables, charts, figures, maps, photographs and other visual materials of whom the copyrights is owned by a third party.
- This manuscript contains no statements that are contradictory to the relevant local and international laws or that infringes on the rights of others.
- I agree to indemnify the Malaysian Journal of Science and the Faculty of Science, University of Malaya (as the publisher) in the event of any claims that arise in regards to the above conditions and assume full liability on the published manuscript.
Reviewer’s Responsibilities
- Reviewers must treat the manuscripts received for reviewing process as confidential. It must not be shown or discussed with others without the authorization from the editor of MJS.
- Reviewers assigned must not have conflicts of interest with respect to the original work, the authors of the article or the research funding.
- Reviewers should judge or evaluate the manuscripts objective as possible. The feedback from the reviewers should be express clearly with supporting arguments.
- If the assigned reviewer considers themselves not able to complete the review of the manuscript, they must communicate with the editor, so that the manuscript could be sent to another suitable reviewer.
Copyright: Rights of the Author(s)
- Effective 2007, it will become the policy of the Malaysian Journal of Science (published by the Faculty of Science, University of Malaya) to obtain copyrights of all manuscripts published. This is to facilitate:
(a) Protection against copyright infringement of the manuscript through copyright breaches or piracy.
(b) Timely handling of reproduction requests from authorized third parties that are addressed directly to the Faculty of Science, University of Malaya. - As the author, you may publish the fore-mentioned manuscript, whole or any part thereof, provided acknowledgement regarding copyright notice and reference to first publication in the Malaysian Journal of Science and Faculty of Science, University of Malaya (as the publishers) are given.
You may produce copies of your manuscript, whole or any part thereof, for teaching purposes or to be provided, on individual basis, to fellow researchers. - You may include the fore-mentioned manuscript, whole or any part thereof, electronically on a secure network at your affiliated institution, provided acknowledgement regarding copyright notice and reference to first publication in the Malaysian Journal of Science and Faculty of Science, University of Malaya (as the publishers) are given.
- You may include the fore-mentioned manuscript, whole or any part thereof, on the World Wide Web, provided acknowledgement regarding copyright notice and reference to first publication in the Malaysian Journal of Science and Faculty of Science, University of Malaya (as the publishers) are given.
- In the event that your manuscript, whole or any part thereof, has been requested to be reproduced, for any purpose or in any form approved by the Malaysian Journal of Science and Faculty of Science, University of Malaya (as the publishers), you will be informed. It is requested that any changes to your contact details (especially e-mail addresses) are made known.
Copyright: Role and responsibility of the Author(s)
- In the event of the manuscript to be published in the Malaysian Journal of Science contains materials copyrighted to others prior, it is the responsibility of current author(s) to obtain written permission from the copyright owner or owners.
- This written permission should be submitted with the proof-copy of the manuscript to be published in the Malaysian Journal of Science
References
Aegerter, M. A., Leventis, N., & Koebel, M. M. (2011). Aerogels handbook: Springer Science & Business Media.
Al-Mothafer, Z., & Abdulmajeed, I. (2021). Comparative study in use sodium silicate instead of NH 4 OH as an alkaline basic catalyst to gelation unmodified silica aerogel based on tetraethoxysilane (TEOS). Journal of Ovonic Research, 17(4).
Al-Mothafer, Z., Abdulmajeed, I., & Al-Sharuee, I. (2021). effect of oxalic acid as a catalyst and dry control chemical additive (dcca) for hydrophilic aerogel base sodium silicate by ambient pressure drying. Journal of Ovonic Research Vol, 17(2), 175-183.
Al-sharuee, I. F. (2019). Thermal Conductivity Performance of Silica Aerogel after Exposition on Different Heating under Ambient Pressure. Baghdad Science Journal, 16(3 (Suppl.)), 0770-0770.
AL-Sharuee, I. F. (2021). Specifications study of Hydrophobic Silica Aerogel Doped with Rhodamine 6G Prepared via Sub-Critical Drying Technique. Iraqi Journal of Science, 483-489.
Al-sharuee, I. F., & Mohammed, F. H. (2019). Investigation study the ability of superhydrophobic silica to adsorb the Iraqi crude oil leaked in water. Paper presented at the IOP Conference Series: Materials Science and Engineering.
Bhagat, S. D., Kim, Y.-H., Suh, K.-H., Ahn, Y.-S., Yeo, J.-G., & Han, J.-H. (2008). Superhydrophobic silica aerogel powders with simultaneous surface modification, solvent exchange and sodium ion removal from hydrogels. Microporous Mesoporous Materials, 112(1-3), 504-509.
Bhagat, S. D., & Rao, A. V. (2006). Surface chemical modification of TEOS based silica aerogels synthesized by two step (acid–base) sol–gel process. Applied Surface Science, 252(12), 4289-4297.
Cheng, Y., Xia, M., Luo, F., Li, N., Guo, C., & Wei, C. s. (2016). Effect of surface modification on physical properties of silica aerogels derived from fly ash acid sludge. Colloids Surfaces A: Physicochemical Engineerin Aspects, 490, 200-206.
Daniel, C., Longo, S., Ricciardi, R., Reverchon, E., & Guerra, G. (2013). Monolithic nanoporous crystalline aerogels. Macromolecular rapid communications, 34(15), 1194-1207.
Dorcheh, A. S., & Abbasi, M. (2008). Silica aerogel; synthesis, properties and characterization. Journal of materials processing technology, 199(1-3), 10-26.
Durães, L., Ochoa, M., Rocha, N., Patrício, R., Duarte, N., Redondo, V., & Portugal, A. (2012). Effect of the drying conditions on the microstructure of silica based xerogels and aerogels. Journal of nanoscience nanotechnology, 12(8), 6828-6834.
Feng, Q., Chen, K., Ma, D., Lin, H., Liu, Z., Qin, S., . . . Aspects, E. (2018). Synthesis of high specific surface area silica aerogel from rice husk ash via ambient pressure drying. Colloids Surfaces A: Physicochemical Engineering spects, 539, 399-406.
He, S., & Chen, X. (2017). Flexible silica aerogel based on methyltrimethoxysilane with improved mechanical property. Journal of Non-Crystalline Solids, 463, 6-11.
He, S., Huang, Y., Chen, G., Feng, M., Dai, H., Yuan, B., & Chen, X. (2019). Effect of heat treatment on hydrophobic silica aerogel. Journal of Hazardous materials, 362, 294-302.
Huang, Y., He, S., Feng, M., Dai, H., Pan, Y., & Cheng, X. (2019). Organic solvent-saving preparation of water glass based aerogel granules under ambient pressure drying. Journal of Non-Crystalline Solids, 521, 119507.
Khedkar, M. V., Somvanshi, S. B., Humbe, A. V., & Jadhav, K. (2019). Surface modified sodium silicate based superhydrophobic silica aerogels prepared via ambient pressure drying process. Journal of Non-Crystalline Solids, 511, 140-146.
Li, M., Jiang, H., Xu, D., Hai, O., & Zheng, W. J. J. o. N.-C. S. (2016). Low density and hydrophobic silica aerogels dried under ambient pressure using a new co-precursor method. 452, 187-193.
Mazrouei-Sebdani, Z., Salimian, S., Khoddami, A., & Shams-Ghahfarokhi, F. (2019). Sodium silicate based aerogel for absorbing oil from water: the impact of surface energy on the oil/water separation. Materials Research Express, 6(8), 085059.
Monshi, A., Foroughi, M. R., & Monshi, M. R. (2012). Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD. World J Nano Sci Eng, , 2: 154, 160.
Nguyen, B. N., Meador, M. A. B., Medoro, A., Arendt, V., Randall, J., McCorkle, L., & Shonkwiler, B. (2010). Elastic behavior of methyltrimethoxysilane based aerogels reinforced with tri-isocyanate. ACS Applied Materials Interface, 2(5), 1430-1443.
Pan, Y., He, S., Cheng, X., Li, Z., Li, C., Huang, Y., & Gong, L. (2017). A fast synthesis of silica aerogel powders-based on water glass via ambient drying. Journal of Sol-Gel Science Technology, 82(2), 594-601.
Sarawade, P. B., Kim, J.-K., Hilonga, A., & Kim, H. T. (2010). Production of low-density sodium silicate-based hydrophobic silica aerogel beads by a novel fast gelation process and ambient pressure drying process. Solid State Sciences, 12(5), 911-918.
Shao, Z., Luo, F., Cheng, X., & Zhang, Y. (2013). Superhydrophobic sodium silicate based silica aerogel prepared by ambient pressure drying. Materials Chemistry, 141(1), 570-575.
Shi, M., Tang, C., Yang, X., Zhou, J., Jia, F., Han, Y., & Li, Z. (2017). Superhydrophobic silica aerogels reinforced with polyacrylonitrile fibers for adsorbing oil from water and oil mixtures. RSC advances, 7(7), 4039-4045.
Shirtcliffe, N., McHale, G., Newton, M., & Perry, C. (2003). Intrinsically superhydrophobic organosilica sol− gel foams. Langmuir, 19(14), 5626-5631.
Wagh, P., Ingale, S., & Gupta, S. C. (2011). New technology for rapid processing and moulding of silica aerogel materials in prescribed shapes and sizes and their characterization. Journal of sol-gel science technology, 58(2), 481-489.
Wang, J., Zhang, Y., Wei, Y., & Zhang, X. (2015). Fast and one-pot synthesis of silica aerogels via a quasi-solvent-exchange-free ambient pressure drying process. Microporous Mesoporous Materials, 218, 192-198.
Wang, X.-D., Sun, D., Duan, Y.-Y., & Hu, Z.-J. (2013). Radiative characteristics of opacifier-loaded silica aerogel composites. Journal of non-crystalline solids, 375, 31-39.
Wingfield, C., Franzel, L., Bertino, M. F., & Leventis, N. (2011). Fabrication of functionally graded aerogels, cellular aerogels and anisotropic ceramics. Journal of Materials Chemistry, 21(32), 11737-11741.
Zhang, X., Chen, Z., Zhang, J., Ye, X., & Cui, S. (2021). Hydrophobic silica aerogels prepared by microwave irradiation. Chemical Physics Letters, 762, 138127.
Zhao, Y., Li, Y., & Zhang, R. (2018). Silica aerogels having high flexibility and hydrophobicity prepared by sol-gel method. Ceramics International, 44(17), 21262-21268.
Zhou, B., Shen, J., Wu, Y., Wu, G., & Ni, X. (2007). Hydrophobic silica aerogels derived from polyethoxydisiloxane and perfluoroalkylsilane. Materials Science Engineering: C, 27(5-8), 1291-1294.